叶绿素铜钠盐染色蚕丝织物动力学研究  

Dyeing Kinetics of Sodium Copper Chlorophyll on Silk

作　　者：侯秀良[1] 杨瑞玲[1] 陈欣子[1] 杨一奇[1] 

机构地区：[1]江南大学生态纺织教育部重点实验室,无锡214122

出　　处：《天然产物研究与开发》2012年第3期312-315,共4页Natural Product Research and Development

基　　金：教育部长江学者和创新团队发展计划(.IRT1135);科技部科技人员服务企业项目(2009GJC10005);江苏省自然科学基金项目(BK2009689);高校科研成果产业化推进工程项目(JH10-30);清华大学艺术与科学研究中心柒牌非物质文化遗产研究与保护基金项目(2010-8)

摘　　要：为提高植物染料叶绿素铜钠盐对蚕丝织物上染过程的控制,提供染色工艺优化的理论指导,本文研究了叶绿素铜钠盐上染蚕丝织物的动力学吸附过程,探讨了染色机理,并运用准一级和准二级动力学模型对叶绿素铜钠盐染色蚕丝织物的实验数据进行模拟,计算叶绿素铜钠盐染色蚕丝织物的动力学参数。结果表明:叶绿素铜钠盐在蚕丝织物上的染色符合准二级动力学模型,且在染色温度70～90℃范围内,随着染色温度的升高,染色平衡吸附量降低,染色速率常数增大,半染时间减小,扩散系数增大。In order to improve the dye up-taking process control and provide a theoretical guidance for dyeing process op- timization of the green vegetable dye sodium copper chlorophyll （SCC） on silk fabrics,the adsorption kinetics of SCC on silk fabrics and the dyeing mechanism were investigated. Pseudo first-order and pseudo second-order kinet/c models were used to fit the experimental data and the adsorption kinetic parameters of SCC on silk fabrics were studied. The results indicated that the adsorption kinetics of SCC on silk fabrics agreed very well with the pseudo second-order kinetic mod- el. In addition,with the increase of the dyeing temperature from 70 ~C to 90 ~C ,the amounts of the dye adsorbed on silk fabrics at adsorption equilibrium was decreased,the dyeing rate constant and the diffusion coefficient were increased and the half dyeing t/me was decreased.

关 键 词：植物染料 叶绿素铜钠盐 蚕丝 染色 动力学 

分 类 号：TS193.11[轻工技术与工程—纺织化学与染整工程]