过渡金属催化氮杂二环烯烃不对称开环反应的研究进展  

Progress in Transition Metal-Catalyzed Asymmetric Ring-Opening Reactions of Azabicyclic Alkenes

作　　者：程汉超[1] 梁秀丽[1] 李晓璐[1] 龙玉华[1] 杨定乔[1] 

机构地区：[1]华南师范大学化学与环境学院,广州510006

出　　处：《有机化学》2012年第3期433-443,共11页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.21172081);广东省自然科学基金(No.8251063101000002)资助项目~~

摘　　要：综述了近年来过渡金属催化氮杂二环烯烃的开环反应的研究进展,重点讨论了过渡金属催化剂的种类、亲核试剂的类型、配体、底物氮杂二环烯烃及其衍生物的结构、溶剂和添加剂等因素对开环反应的影响,并对开环反应的可能的机理进行了讨论.The recent progress in transition metal-catalyzed ring-opening reactions of azabicyclic alkenes was reviewed focused on the influence of the types of transition metal catalysts,nucleophiles,ligands,the structures of azabicyclic alkenes and its derivatives,solvents and additives on the ring-opening reactions.Moreover,the possible mechanisms of the ring-opening reactions were also discussed.

关 键 词：氮杂二环烯烃 过渡金属 催化 开环反应 

分 类 号：O621.25[理学—有机化学]