一种新型水溶性聚苯胺衍生物的化学合成  

Chemical Synthesis of a Novel Water-soluble Polyaniline Derivative

作　　者：郑时国[1] 辜天彬[1] 詹豪强[1] 刘向凯[1] 张亚丽[1] 夏世威[1] 

机构地区：[1]化学合成与污染控制四川省重点实验室西华师范大学化学化工学院,四川南充637009

出　　处：《西华师范大学学报（自然科学版）》2012年第1期96-101,共6页Journal of China West Normal University(Natural Sciences)

基　　金：西华师范大学科研启动经费项目(10B002)

摘　　要：报道了一种新型水溶性聚苯胺衍生物的化学合成,并通过红外光谱、紫外-可见光谱、循环伏安法、X-射线衍射和溶解率测定对其结构与性能进行了研究.研究结果表明:这种聚苯胺衍生物共轭性差,不具有电活性,可能是不导电的;呈现出非晶态结构;在水、乙醇、氯仿、N,N-二甲基甲酰胺等普通溶剂中具有较好的溶解性.In this paper,the chemical synthesis of a novel water-soluble polyaniline derivative was reported and its structure and properties were studied by FTIR,UV-Vis,XRD,cyclic voltammetry and determination of solubility.The results indicated that this polyaniline derivative was poorly conjugated,had no electroactivity,exhibited an amorphous structure,and had preferable solublity in some common solvents like water,ethanol,chloroform and N,N-dimethyl formamide,etc.

关 键 词：聚苯胺 水溶性聚合物 聚合 共轭 

分 类 号：O633.21[理学—高分子化学]