A New 1D Zinc Coordination Polymer Constructed by 1-Naphthylacetate and 4,4'-bpy:Synthesis,Structure and Luminescent Property  

作　　者：周建敏 牛显春 

机构地区：[1]College of Chemistry and Life Science,Guangdong University of Petrochemical Technology [2]College of Chemical and Environmental Engineering,Guangdong University of Petrochemical Technology

出　　处：《Chinese Journal of Structural Chemistry》2012年第3期361-366,共6页结构化学（英文）

基　　金：supported by the Guangdong University of Petrochemical Technology

摘　　要：One new zinc coordination polymer,[Zn（NAA）2（4,4＇-bpy）]n（1,HNAA = 1-naphthaleneacetic acid,4,4＇-bpy = 4,4＇-bipyridine）,has been synthesized under hydrothermal conditions and characterized by elemental analysis,IR spectroscopy,thermogravimetric analysis（TGA）,and single-crystal X-ray diffraction.Coordination polymer 1 is of monoclinic system,space group Cc with a = 9.8720（6）,b = 16.7397（9）,c = 17.0371（12） ,β = 104.8080（10）°,V = 2721.9（3）3,C34H26N2O4Zn,Z = 4,Mr = 591.94,Dc = 1.444 g/cm3,μ（MoKα） = 0.946 mm-1,F（000） = 1224,the final R = 0.0282 and wR = 0.0720 for 3300 observed reflections with I 〉 2σ（I）.1 exhibits an interesting one-dimensional chain structure.Furthermore,the luminescent property of 1 has also been investigated.One new zinc coordination polymer,[Zn（NAA）2（4,4＇-bpy）]n（1,HNAA = 1-naphthaleneacetic acid,4,4＇-bpy = 4,4＇-bipyridine）,has been synthesized under hydrothermal conditions and characterized by elemental analysis,IR spectroscopy,thermogravimetric analysis（TGA）,and single-crystal X-ray diffraction.Coordination polymer 1 is of monoclinic system,space group Cc with a = 9.8720（6）,b = 16.7397（9）,c = 17.0371（12） ,β = 104.8080（10）°,V = 2721.9（3）3,C34H26N2O4Zn,Z = 4,Mr = 591.94,Dc = 1.444 g/cm3,μ（MoKα） = 0.946 mm-1,F（000） = 1224,the final R = 0.0282 and wR = 0.0720 for 3300 observed reflections with I 〉 2σ（I）.1 exhibits an interesting one-dimensional chain structure.Furthermore,the luminescent property of 1 has also been investigated.

关 键 词：zinc coordination polymer crystal structure LUMINESCENT 

分 类 号：O634[理学—高分子化学]