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机构地区:[1]新疆大学地质与勘查工程学院,乌鲁木齐830047
出 处:《矿物岩石地球化学通报》2012年第2期121-127,151,共8页Bulletin of Mineralogy, Petrology and Geochemistry
基 金:国家自然科学基金资助项目(40862004);新疆重点学科矿产普查及勘探建设项目资助;新疆高校科学研究重点项目(XJEDV2007I09)联合资助
摘 要:本文通过XRF和ICP-MS测试方法对油页岩样品进行测试,根据常量元素和微量元素特征、组分含量及某些元素的比值,探讨了研究区油页岩样品的地球化学特征,进一步阐述了其沉积环境的指示意义。结果表明,P和B元素强烈富集,相当硼及古盐度值都表明属于半咸水沉积环境,B/Ga、Sr/Ba值也说明受到海水影响或间歇性受海水影响,沉积环境以半咸水湖泊为主;Fe2+/Fe3+、V/(V+Ni)、V/Ni、Cu/Zn、Ni/Co和U/Th值及Ni的含量说明沉积环境为咸化的弱还原-还原环境;Mn/Fe和Mn/Ti值也较小,反映近岸的沉积环境;Sr/Cu表明主力油页岩形成时期处于温湿-干热气候。总体上反映出,研究区油页岩的沉积介质环境的显著特征是半咸水状态的弱还原-还原环境。On the basis of XRF and ICP-MS analyses for the Lucaogou Formation oil shale samples,this paper investigated geochemical characteristics,including,features of major and trace elements,elements contents and several element-ratios,of the oil shale samples and discussed their implications on rebuilding sedimentary environment history.The results showed that P and B are significantly enriched,together with the value of paleosalinity,indicate a brackish water sedimentary environment;the ratios of B/Ga and Sr/Ba show that the sedimentary environment was affected or intermittently affected by sea water;the ratios of Fe2+/Fe3+,V/(V+Ni),V/Ni,Cu/Zn,Ni/Co and Ni illustrate that sedimentary environment is a salinized weak reducing to reducing environment;the ratios of Mn/Fe and Mn/Ti are small reflecting a near shore sedimentary environment;Sr/Cu value shows that the climate of the main formation period was warm/humid-dry/hot.In summary,the sedimentary environment of oil shale forming can be characterized as brackish water weak reducing-reducing sedimentary environment.
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