新型的香豆素染料/碘鎓盐光敏引发系统的研究  

STUDY OF A NOVEL PHOTOSENSITIVE INITIATING SYSTEM OF COUMARIN DYE/IODONIUM SALT

作　　者：高放[1] 杨永源[1] 

机构地区：[1]中国科学院感光化学研究所,北京100101

出　　处：《高分子学报》2000年第1期125-127,共3页Acta Polymerica Sinica

基　　金：国家自然科学基金!资助( 基金号59773011)

摘　　要：The photosensitive initiating system composed of 7 diethylamino 3 (2’ N methylbenzimidazolyl)coumarin dye (DBC) as sensitizer and diphenyliodonium hexafluorophosphate (DIH) as initiator,can be used to initiate the polymerization of methyl methacrylate (MMA) in visible light.When exposed to visible light,coumarin dye/iodonium salt undergoes quick electron transfer from DBC to DIH and free radicals are produced.The visible light photoinduced reaction between DBC and DIH is mainly through the excited singlet state of DBC and thus it is little sensitive to O 2.The fluorescence of DBC can be quenched efficiently by DIH and the change is in accord with Stern Volmer equation and the quench constant K q can reach 10 12 M -1 S -1 .The influence of concentration of DBC on the polymerization rate of MMA shows that coumarin free radical act mainly as chain terminator in polymerization and has a stronger tendency to terminate the chain reaction.The photosensitive initiating system composed of 7 diethylamino 3 (2’ N methylbenzimidazolyl)coumarin dye (DBC) as sensitizer and diphenyliodonium hexafluorophosphate (DIH) as initiator,can be used to initiate the polymerization of methyl methacrylate (MMA) in visible light.When exposed to visible light,coumarin dye/iodonium salt undergoes quick electron transfer from DBC to DIH and free radicals are produced.The visible light photoinduced reaction between DBC and DIH is mainly through the excited singlet state of DBC and thus it is little sensitive to O 2.The fluorescence of DBC can be quenched efficiently by DIH and the change is in accord with Stern Volmer equation and the quench constant K q can reach 10 12 M -1 S -1 .The influence of concentration of DBC on the polymerization rate of MMA shows that coumarin free radical act mainly as chain terminator in polymerization and has a stronger tendency to terminate the chain reaction.

关 键 词：染料敏化 光敏聚合 香豆素 碘Wing盐 

分 类 号：O633.5[理学—高分子化学]