温度梯度法生长Tm^(3+):BaY_2F_8晶体的光谱特性  

Spectral Properties of Tm^(3+)-Doped BaY_2F_8 Crystals Grown by Temperature Gradient Method

作　　者：王帅[1] 阮永丰[1] 张守超[2] 李文润[1] 王友发[1] 吴周礼[1] 童红双[1] 

机构地区：[1]天津大学理学院,天津300072 [2]天津城建学院,天津300384

出　　处：《硅酸盐学报》2012年第4期595-600,共6页Journal of The Chinese Ceramic Society

摘　　要：采用温度梯度法成功生长出BaY2F8晶体和Tm3+:BaY2F8晶体。测试了Tm3+:BaY2F8晶体的室温吸收光谱和室温、低温荧光光谱;根据Judd–Ofelt理论,拟合出晶体场强度参数i(i=2,4,6)为:2=0.364 1×10–20cm2,4=5.750 9×10–20cm2,6=2.533 9×10–20cm2。计算并分析了Tm3+:BaY2F8晶体各激发能级的自发辐射跃迁几率、荧光分支比、荧光寿命和积分发射截面积等光谱参量,从计算的结果可以看出3F4→3H6跃迁有较大的荧光寿命、积分发射截面,易于实现人眼安全波段的激光震荡。结合室温和低温的荧光发射谱,定性阐述了随着温度的降低,荧光发射峰的强度增强,并且主要发射峰的半峰宽变窄。The laser crystal Tm3＋：BaY2F8 and BaY2F8 were grown by temperature gradient method.The absorption and emission spectra of Tm3＋：BaY2F8 crystal at room temperature were measured and studied.Based on Judd–Ofelt theory,the intensity parameters of Ωi（i = 2,4,6） have been fitted and values are： Ω2 = 0.364 1 × 10–20 cm2,Ω4 = 5.750 9 × 10–20 cm2,Ω6 = 2.533 9 × 10–20 cm2.The values of radiative probabilities,radiative lifetime and integrated emission cross-sections of Tm3＋-doped BaY2F8 crystal were calcu-lated.The results indicate that the eye-safe laser can be obtained because of the larger radiative lifetime and integrated emission cross-section of the 3F4→3H6 transition.The emission spectra at low temperature show that the intensity of the emission peak in-creases with decreasing temperature,while the FWHM becomes narrower.

关 键 词：铥掺杂氧化钇钡晶体 晶体生长 温度梯度法 光谱特性 Judd–Ofelt理论 

分 类 号：O782[理学—晶体学]