CoPc(β-OC_6Cl_5)_4/SnO_2复合材料的制备及表征  

Preparation and characteration of β-tetra-pentachlorophenyloxy-Cobalt Phthalocyanine/SnO_2 nanocomposite

作　　者：尹彦冰[1] 孙季如[1] 任卉蕾[1] 牟海涛[1] 

机构地区：[1]齐齐哈尔大学化学与化学工程学院,黑龙江齐齐哈尔161006

出　　处：《高师理科学刊》2012年第2期53-56,共4页Journal of Science of Teachers＇College and University

基　　金：黑龙江省普通高等学校青年学术骨干支持计划项目(1153G052)

摘　　要：采用原位合成的方法制备CoPc(β-OC6Cl5)4/SnO2复合材料,利用UV,IR,XRD对产物进行表征.结果表明,CoPc(β-OC6Cl5)4/SnO2复合材料在紫外光谱中出现了酞菁特征吸收Q带的红移,红外光谱中出现了M-O的振动吸收峰,并且在XRD图谱中显现出SnO2晶粒变小,这说明CoPc(β-OC6Cl5)4与SnO2之间形成部分化学键.β-tetra-pentachlorophenyloxy-Cobalt Phthalocyanine/SnO2 nanocomposite were synthesized by in-situ process.The products were characterized by means of UV,IR and XRD methods.The experimental results indicate that different degree of red shift on the Q band with maximum absorption of the substitute phthalocyanine occurred,the vibration absorption peaks of M-O appreared in IR spectrum,and the size of crystal particals have become smaller than before in XRD spectrum,all that show the complex of tetra-pentachlorophenyloxy Cobalt Phthalocyanines and SnO2were linked with partial chemical bond.

关 键 词：原位合成 复合材料 二氧化锡 

分 类 号：TQ423.11[化学工程]