1,1–二氨基–2,2–二硝基乙烯的合成研究进展  

Research Progress in Synthesis of 1,1-Diamino-2,2-Dinitroethylene

作　　者：冯晓晶[1] 马会强[1] 张寿忠[1] 苗成才[1] 马英华[1] 

机构地区：[1]黎明化工研究院,河南洛阳471000

出　　处：《化学推进剂与高分子材料》2012年第2期24-29,共6页Chemical Propellants & Polymeric Materials

摘　　要：1,1–二氨基–2,2–二硝基乙烯(FOX–7)作为含能材料中典型的炸药,因具有高能钝感的特性,其合成方法受到广泛的关注。主要介绍了国内外近年来合成FOX–7的3条反应路线及改进方法,通过对各种合成方法的比较,认为采用2–甲基–4,6–二羟基嘧啶为原料改进的2–甲基–4,6–嘧啶二酮法具有应用潜力,并对FOX–7的应用前景进行了展望。As a typical explosive in energetic materials,there is a wide focus on the synthesis methods of 1,1-diamino-2,2-dinitroethylene（FOX-7） due to its high energy and low sensitivity.Three reaction routes and improved methods for preparing FOX-7 at home and abroad in recent years are mainly introduced.Compared with various synthesis methods,it is considered that the improved 2-methyl-4,6-pyrimidinedione method using 2-methyl-4,6-dihydroxy pyrimidine as raw material has application potential.The application prospect of FOX-7 is predicted.

关 键 词：1 1–二氨基–2 2–二硝基乙烯 FOX–7 钝感炸药 合成方法 研究进展 

分 类 号：TQ564[化学工程—炸药化工]