Design,Synthesis and Electrochromic Properties of Anthraquinone Imide-based Donor-acceptor Type of Near Infrared Chromophores  

作　　者：QIAO Wen-qiang 

机构地区：[1]Key Laboratory of Materials Behaviors and Evaluation Technology in Space Environments,Harbin Institute of Technology,Harbin 150001,P.R.China

出　　处：《Chemical Research in Chinese Universities》2012年第2期239-241,共3页高等学校化学研究（英文版）

基　　金：Supported by the Development Program for Outstanding Young Teachers in Harbin Institute of Technology,China(No.HITQNJS.2009.020).

摘　　要：A new series of near infrared（NIR） electrochromic anthraquinone imides containing a triphenylamine moiety as an electron donor was synthesized and their electrochemical and spectroelectrochemical behavior were investigated.The results show that the new anthraquinone imides are redox active which can be reduced electrochemically from the neutral state to the radical anion form that absorbs in a range of 700―1200 nm.A new series of near infrared（NIR） electrochromic anthraquinone imides containing a triphenylamine moiety as an electron donor was synthesized and their electrochemical and spectroelectrochemical behavior were investigated.The results show that the new anthraquinone imides are redox active which can be reduced electrochemically from the neutral state to the radical anion form that absorbs in a range of 700―1200 nm.

关 键 词：Anthraquinone imide Triphenylamine moiety Near infrared electrochromism 

分 类 号：O623.626[理学—有机化学] O657.33[理学—化学]