Cu(Ⅱ))的丙烯酸桥联双核配合物及醋酸、2,4,6-三甲基吡啶三元配合物的合成与表征  

Synthesis and characterization of acrylate-bridged dinuclear copper complex and acetate and 2,4,6-trimethylpyridine copper complex

作　　者：钱永[1,2] 王建军[1] 

机构地区：[1]苏州科技学院化学与生物工程学院,江苏苏州215009 [2]江苏省环境功能材料重点实验室,江苏苏州215009

出　　处：《苏州科技学院学报（工程技术版）》2012年第1期76-80,共5页Journal of Suzhou University of Science and Technology （Engineering and Technology）

基　　金：住房和城乡建设部科学技术项目(2011-K4-2);苏州市应用基础研究计划项目(SYG201123);环境化学与生态毒理学国家重点实验室开放基金项目(KF2010-11)

摘　　要：在温和条件下合成了Cu(Ⅱ)的丙烯酸双核配合物[Cu2(C3H3O2)4].H2O和醋酸、2,4,6-三甲基吡啶三元配合物[Cu(C2H3O2)2(C8H11N)2]。通过元素分析、红外光谱、紫外光谱和核磁测试表征了该两种配合物的组成和结构,并用溶解度、电导率测试等物理化学手段对配合物的物理化学性质进行了初步研究。The acrylate-bridged dinuclear copper complex [Cu2（C3H3O2）4]·H2O and acetate and 2,4,6-Trimethylpyridine copper complex [Cu（C2H3O2）2（C8H11N）2] were synthesized under tender conditions in this paper.The elemental components and structures of the two complexes were characterized and confirmed by elemental analyses,FT-IR,UV-Vis and 1H NMR.And the primary investigation on the physical and chemical characteristics of the two complexes has been carried out through some physical and chemical methods such as the solubility and molar conductivity in this work.

关 键 词：Cu(Ⅱ) 丙烯酸 醋酸 吡啶 配合物 

分 类 号：O641.4[理学—物理化学]