有机膦功能化联咪唑的合成与表征  

Synthesis and Characterization of Phosphine-Fuctionalized Biimidazole

作　　者：郭苗[1] 张涛[1] 陈波[1] 梁洪泽[1] 雷克微[1] 

机构地区：[1]宁波大学材料科学与化学工程学院,宁波315211

出　　处：《有机化学》2012年第4期799-801,共3页Chinese Journal of Organic Chemistry

基　　金：浙江省自然科学基金(No.Y4100113);宁波市自然科学基金(No.2010A610027);宁波大学王宽诚幸福基金资助项目~~

摘　　要：从N,N'-二烷基酯联咪唑出发,经过还原、氯代、亲核取代反应,合成了N,N'-二烷基膦联咪唑.产物经过了红外、核磁共振及质谱表征.反应前体N,N'-二醇联咪唑和N,N'-二烷基氯联咪唑可作为起始物,合成得到一系列联咪唑衍生物.tarting from N,N＇-biimidazolyl diesters,N,N＇-biimidazolyl diphosphine was synthesized by sequent reactions of reduction,chlorination and nucleophilic substitution.It has been characterized by IR,NMR and MS techniques.The two precursors of N,N＇-biimidazolyl alcohol and N,N＇-biimidazolyl chloride can be further functionalized and thus provide opportunities to synthesize a series of biimidazole derivatives.

关 键 词：合成 联咪唑 有机膦化合物 

分 类 号：O627.51[理学—有机化学]