基于半经验模型对大面积染料敏化太阳电池性能影响因素的研究  

Study of influencing factors for performance of large-scale dye-sensitized solar cells based on the semi-empirical model

作　　者：吴宝山[1] 王琳琳[1] 汪咏梅[1] 马廷丽[1] 

机构地区：[1]大连理工大学化工学院精细化工国家重点实验室,大连116024

出　　处：《物理学报》2012年第7期553-559,共7页Acta Physica Sinica

基　　金：国家自然科学基金(批准号:50773008);国家高技术研究发展计划863计划项目(批准号:2009AA03Z220)资助的课题~~

摘　　要：以影响大面积染料敏化太阳电池性能的几个物理参量和几何参量为切入点,分析了内部电阻对电池性能的影响,针对几种构型不同的大面积电池,建立了效率的半经验模型.根据并联、串联、和各单元独立式串并联的大面积电池的相关物理参量和几何参量,对电池效率进行了计算.通过比较计算值与测试值的偏差,分析了半经验模型的适用性.在半经验模型的基础上,分析了相关物理参量和几何参量对电池性能的影响.结果表明,在实际应用中,通过半经验模型分析物理参量和几何参量的影响,可以优化大面积电池的性能.Based on some physical and geometric parameters,the influence of internal resistance on the cell performance is analyzed and a semi-empirical mathematical model of the efficiency is built for some configurations of large-scale dye-sensitized solar cells.Three configurations of large-scale cells are investigated,in which the independent units are connected in series and in parallel,as well as in series-parallel.The efficiencies of the three-type large-scale cells are calculated according to their physical and geometric parameters. The applicability of the model is analyzed by comparing the calculated efficiencies with the measured ones.The influences of the physical and geometric parameters on the cell performance are investigated based on the semi-empirical mathematical model.It is found that the optimization of the performance of large-scale cells can be carried by analyzing the influences of physical and geometric parameters using the semi-empirical mathematical model.

关 键 词：染料敏化 太阳电池 大面积 半经验模型 

分 类 号：TM914.4[电气工程—电力电子与电力传动]