新型四苯基卟啉衍生物及其锌(Ⅱ)配合物的合成与性质研究  

Synthesis and properties of tetraphenylporphyrin derivative and zinc(Ⅱ)-tetraphenylporphyrin complex

作　　者：李小康[1,2] 贺晓慧[1] 陈义旺[1] 范小林[2] 

机构地区：[1]南昌大学高分子研究所,南昌330031 [2]赣南师范学院,江西省有机药物化学重点实验室,赣州341000

出　　处：《化工新型材料》2012年第4期106-108,共3页New Chemical Materials

基　　金：国家自然科学基金(50568001);江西省教育厅科技基金(GJJ09576)

摘　　要：以四苯基卟啉(TPP)为原料,经过硝化、还原、酰胺化等反应合成了一种新型四苯基卟啉衍生物及其锌(Ⅱ)配合物,通过FAB-MS、IR、1 H-NMR和元素分析等方法鉴定了目标产物的结构,并对其发光性质进行了研究。结果表明,四苯基卟啉衍生物及其锌(Ⅱ)配合物的紫外-可见光谱和荧光光谱均发生了明显红移。Tetraphenylporphyrin derivative and zinc（Ⅱ）-tetraphenylporphyrin complex had been designed and synthesized from tetraphenylporphyrin（TPP） via nitration,reduction and amidation reactions.The structures of the intermediates and target compounds were confirmed by FAB-MS,IR,1H NMR,and element analysis.The UV-vis and fluorescence spectra of tetraphenylporphyrin derivative and zinc（Ⅱ）-tetraphenylporphyrin complex were investigated,and the results showed that an obvious bathochromic shift and displayed a strong fluorescence of tetraphenylporphyrin derivative and zinc（Ⅱ）-tetraphenylporphyrin complex.

关 键 词：四苯基卟啉 卟啉锌配合物 紫外-可见 荧光 

分 类 号：O627.23[理学—有机化学]