Green,mild and efficient bromination of aromatic compounds by HBr promoted by trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane in water as a solvent  

作　　者：Kaveh Khosravi Samira Kazemi 

机构地区：[1]Department of Chemistry,Faculty of Science,University of Arak [2]Department of Chemistry,Shahr-e-Rey branch,Islamic Azad University

出　　处：《Chinese Chemical Letters》2012年第4期387-390,共4页中国化学快报（英文版）

摘　　要：A combination of HBr and trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane as anew and powerful oxidant was found effective for facile brotnination of different aromatic compounds at room temperature in water as a green solvent.Mild reaction conditions,high selectivity and yield,high reaction rate and non-toxicity are some of the major advantages of this synthetic protocol.A combination of HBr and trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane as anew and powerful oxidant was found effective for facile brotnination of different aromatic compounds at room temperature in water as a green solvent.Mild reaction conditions,high selectivity and yield,high reaction rate and non-toxicity are some of the major advantages of this synthetic protocol.

关 键 词：Trans-3 5-dihydroperoxy-3 5-dimethyl-1 2-dioxolane HBR BROMINATION Anilines Phenoles 

分 类 号：O621.25[理学—有机化学]