电感耦合等离子体原子发射光谱法测定防锈铝合金中痕量钠  

ICP-AES Determination of Trace Amounts of Sodium in Anticorrosive Aluminum Alloy

作　　者：李芬[1] 李启华 周西林 马英 樊朝英 

机构地区：[1]重庆工业职业技术学院化学工程系,重庆401120 [2]兵器工业西南地区理化检测中心,重庆400020 [3]重庆宗申发动机制造有限公司理化中心,重庆400054

出　　处：《理化检验（化学分册）》2012年第4期465-466,470,共3页Physical Testing and Chemical Analysis(Part B:Chemical Analysis)

摘　　要：提出了电感耦合等离子体原子发射光谱法测定防锈铝合金中痕量钠的方法。以盐酸(1+1)溶液和过氧化氢溶解样品,选择波长588.995 nm为钠的分析线。方法的检出限(3S/N)为0.028 mg.L-1。方法用于测定防锈铝合金中痕量钠(wNa=0.000 14%～0.000 73%),加标回收率在91.4%～113.3%之间,相对标准偏差(n=6)在2.6%～5.5%之间。An ICP-AES method for the determination of sodium in anticorrosive aluminum alloy was proposed. The sample was dissolved with HCI（1＋1） and H2O2. The wavelength of 588. 995 nm was selected as analytical line for the determination of sodium. Detection limit （3S/N） of the method found was 0. 028 mg. L^-1. The proposed method was applied to the analysis of trace amounts of sodium in anticorrosive aluminum alloy （wNa=0. 000 14%-0. 000 73%）, giving values of recovery obtained by standard addition method in the range of 91.4%-113.3% and RSD＇s （n=6） in the range of 2.6%-5.5%.

关 键 词：电感耦合等离子体原子发射光谱法 防锈铝合金 钠 

分 类 号：O657.31[理学—分析化学]