催化合成环保增塑剂的研究及其应用进展  

Research and application progress of the catalytic synthesis of environmental plasticizers

作　　者：蒋平平 张书源 冷炎 董玉明 张萍波 

机构地区：[1]江南大学化学与材料工程学院,江苏无锡214122

出　　处：《化工进展》2012年第5期953-964,共12页Chemical Industry and Engineering Progress

基　　金：国家十二五科技支撑项目(2012BAD32B03)

摘　　要：综述了国内外催化合成新型增塑剂的新方法和催化反应工艺、催化剂的种类和制备,重点介绍了国内外主要新型环保增塑剂的性能、应用及研究现状,包括生物基植物油、聚酯、柠檬酸酯、偏苯三酸三酯及对苯二甲酸二辛酯类增塑剂的合成与性能,并与传统合成方法及催化剂比较,指出了我国催化合成增塑剂的趋势和增塑剂在国家高新技术领域中应用方向,提出我国增塑剂行业及新材料助剂领域的发展应着重于调整产品结构,加快非邻苯结构类、植物油基增塑剂的开发。New methods of catalytic synthesis of novel plasticizer, catalytic reaction process, catalyst type and preparation were summarized. Properties of major domestic and overseas new environmental protection plasticizers, applications and the research status were especially focused on, including the synthesis and properties of biological-base vegetable oil plasticizer, polyester plasticizer, citric acid ester plasticizer, trioctyl trimellitate plasticizer and dioctyl terephthalate plasticizer. At the meantime, compared with the traditional synthesis method and catalyst, the trend of catalytic synthesis of plasticizer and the application direction of plasticizers in national high-tech fields were pointed out. Put forward the plasticizer industry and new materials additive field in our country development should focus on the adjustment of product structure, accelerate the exoloitation of non adjacent benzene structure, r^lant oil base nlastieizer_

关 键 词：环保增塑剂 酯化反应 PVC助剂 生物基增塑剂 催化剂 

分 类 号：TQ414[化学工程]