Michael Addition Reaction of Fluorinated Nitro Compounds  

作　　者：郇凤 胡华伟 黄焰根 陈庆云 郭勇 

机构地区：[1]Key Laboratory of Organofluorine Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China [2]College of Chemistry,Chemical Engineering and Biotechnology,Donghua University,Shanghai 201620,China

出　　处：《Chinese Journal of Chemistry》2012年第4期798-802,共5页中国化学（英文版）

摘　　要：The Michael addition reactions of fluorinated nitro compounds with electron deficient olefins to give γ-fiuoro-γ-nitro-esters, nitriles and ketones which bear a fluorinated quaternary carbon center were reported. The reactions were promoted by TMG, affording the desired adducts in acceptable to good yields.The Michael addition reactions of fluorinated nitro compounds with electron deficient olefins to give γ-fiuoro-γ-nitro-esters, nitriles and ketones which bear a fluorinated quaternary carbon center were reported. The reactions were promoted by TMG, affording the desired adducts in acceptable to good yields.

关 键 词：Michael addition reaction fluorinated nitro compounds fluorinated quaternary carbon center 

分 类 号：TQ246.1[化学工程—有机化工] O621.256.7[理学—有机化学]