疏水型二氧化硅粒子对泡沫体系稳定性的影响  

Influence of hydrophobically modified silicon dioxide particles on stability of EOR flooding foam

作　　者：茹冕[1] 常志东[1] 罗文利[2] 李文军[1] 顾少楠[1] 张永强[1] 邱红[1] 牛佳玲[2] 

机构地区：[1]北京科技大学化学与化学工程系,北京100083 [2]中国石油勘探开发研究院,北京100083

出　　处：《化工学报》2012年第6期1943-1950,共8页CIESC Journal

基　　金：国家自然科学基金项目(20876157);中国石油天然气股份有限公司'十二五'油气田开发科技项目'三次采油提高采收率技术研究'专项(2011B-1303)~~

摘　　要：对市售二氧化硅粒子进行疏水改性,分别用改性前和改性后的二氧化硅粒子与十二烷基硫酸钠制备泡沫分散液,探讨了二氧化硅粒子亲、疏水性,粒子浓度,粒子在气液界面膜上的吸附量以及动态拉伸条件下的液膜稳定性的变化规律。研究结果表明,在搅拌条件下,与改性后粒子相比,改性前粒子对维持泡沫体系的起泡性和稳定性作用较强。泡沫稳定性随二氧化硅粒子质量分数的增加而增大,在粒子浓度为0.05%时达到最大值。在拉伸条件下,改性后粒子对液膜稳定性的增强效果优于改性前粒子的作用。改性后二氧化硅粒子质量分数为0.05%的分散液的液膜拉伸最长。The surface of commercial silicon dioxide particles was hydrophobically modified.The aqueous foams were prepared by stirring mixtures of dodecyl sulfate sodium（SDS） and silicon dioxide particles before or after surface modification.Hydrophobicity of particles,particle additions,concentration of particles adsorbed on the air/water interface and stability of dynamic stretching liquid film were investigated.The results showed that the foamability and foam stability of the original silica/SDS dispersion was better than that of the modified silica particle/SDS dispersion.The foam stability increased with increasing particle addition and it reached a maximum with the particle addition of 0.05%（mass）.However,in dynamic stretching conditions,the liquid film can be stabilized by hydrophobically modified silica particles.The stretch length of liquid film reached a maximum at the particles addition of 0.05%.

关 键 词：泡沫 稳定性 二氧化硅粒子 疏水性 拉伸 

分 类 号：TE357[石油与天然气工程—油气田开发工程]