Fretting wear and friction oxidation behavior of 0Cr20Ni32AlTi alloy at high temperature  

0Cr20Ni32AlTi合金的高温微动磨损及摩擦氧化特性(英文)

作　　者：张晓宇[1] 任平弟[1] 钟发春[2] 朱旻昊[1] 周仲荣[1] 

机构地区：[1]西南交通大学牵引动力国家重点实验室,成都610031 [2]中国工程物理研究院化工材料研究所,绵阳621900

出　　处：《Transactions of Nonferrous Metals Society of China》2012年第4期825-830,共6页中国有色金属学报（英文版）

基　　金：Project (51075342) supported by the National Natural Science Foundation of China;Project (2007CB714704) supported by the National Basic Research Program of China

摘　　要：The fretting wear behavior of 0Cr20Ni32AlTi alloy was investigated with crossed cylinder contact under 80 N at 300 and 400 °C.Wear scar and debris were analyzed systematically by scanning electron microscopy and X-ray photoelectron spectroscopy.The results show that the friction logs are mixed fretting regime and gross slip regime with the magnitudes of displacement of 10 and 20 μm,respectively.Severe wear and friction oxidation occur on the material surface.A large number of granular debris produced in the fretting process can be easily congregated and adhered at the contact zone after repeated crushes.The resultant of friction oxidation is mainly composed of Fe3O4,Fe2O3,Cr2O3 and NiO.Temperature and friction are the major factors affecting the oxidation reaction rate.The fretting friction effect can enhance the oxidation reaction activity of surface atoms of 0Cr20Ni32AlTi alloy and reduce the oxidation activation energy.As result,the oxidation reaction rate is accelerated.在300和400℃、载荷80N的条件下,将0Cr20Ni32AlTi合金以水平垂直交叉接触方式进行微动磨损试验,并采用SEM和XPS对磨痕及磨屑进行分析。结果表明:当位移幅值为10和20μm时,微动分别对应于混合区和滑移区,且材料表面均发生严重的磨损和摩擦氧化。微动过程产生大量颗粒状磨屑,经往复碾压后易粘附、聚集于接触区。摩擦氧化反应的生成物主要由Fe3O4、Fe2O3、Cr2O3和NiO等组成。温度和摩擦作用是影响磨屑氧化转化反应速率的主要因素。微动摩擦作用可以增加0Cr20Ni32AlTi合金表面原子的氧化反应活性并降低氧化反应的活化能,从而加快磨屑氧化转化反应的速率。

关 键 词：high temperature nickel chrome-iron alloy fretting wear friction oxidation activation energy 

分 类 号：TG146[一般工业技术—材料科学与工程]