酰胺基卟啉的制备,光谱及电化学性质研究  

Preparation,spectroscopic and electrochemical property of an imide porphyrin

作　　者：庄长福[1] 王瑛[1] 张加研[1] 吴春华[1] 秦永剑[1] 师同顺[2] 

机构地区：[1]西南林业大学材料工程学院,云南昆明650224 [2]吉林大学化学学院,吉林长春130023

出　　处：《化学研究与应用》2012年第5期750-754,共5页Chemical Research and Application

基　　金：国家自然科学基金项目(31060099)资助;云南省自然科学基金项目(2010ZC093)资助;云南省教育厅科学研究基金重点项目(2010Z040)资助;西南林业大学重点学科建设项目(XKX200907)资助

摘　　要：合成了未见文献报道的5-(4-异烟酸酰亚胺基)苯基-10,15,20-三苯基卟啉配体(H2P)及其锌配合物(ZnP),并通过紫外-可见光谱、红外光谱、核磁共振氢谱、元素分析等测试方法对化合物的结构加以确认。研究表明,配体和配合物的拉曼光谱有很大区别,卟啉配体的循环伏安曲线与氨基卟啉和锌配合物不同,卟啉环的氧化还原峰位都有移动。差热研究表明,卟啉配体410oC开始分解,显示了很高的热稳定性。In this paper, the new 5-（4-isonicotinicaminophenyl）-10, 15,20-triphenylporphyrin ligand （H2P） and its compound （ZnP） had been synthesized and confirmed by means of elemental analyses, UV-Vis spectra, FT-IR spectra and 1H NMR spectra. The results showed that there were much difference between the ligand and the compound of the raman spectra. The cyclic voltammetry of the ligand was different from MATPP and ZnP,which showed the values of the redox potentials were shifted. The thermal studies showed that the porphyrin ligand had higher thermal stability and could be dried under 410℃.

关 键 词：卟啉 配合物 拉曼光谱 电化学 

分 类 号：O641.2[理学—物理化学]