环氧蓖麻油合成研究  

Synthesis of Epoxidized Castor Oil

作　　者：侯宾[1] 向开权[1] 黄东海[1] 杨艳[1] 

机构地区：[1]湖北民族学院化学与环境工程学院,湖北恩施445000

出　　处：《湖北民族学院学报（自然科学版）》2012年第2期163-166,169,共5页Journal of Hubei Minzu University(Natural Science Edition)

基　　金：湖北省自然科学基金项目(2010CDZ064);湖北民族学院博士启动基金项目(MY2009B014);湖北民族学院大学生创新项目(2011CY011)

摘　　要：以磷酸为催化剂、采用过氧乙酸法对蓖麻油(CO)进行环氧化研究,探索了反应时间、反应温度和双氧水的用量等变量参数对蓖麻油环氧化的影响,得到各变量参数对反应的影响大小为:时间>温度>酸量>双氧水的量>催化剂的浓度.利用FI-IR对环氧蓖麻油(ECO)进行了表征,然后对比了CO和ECO的TG和DTG热稳定性.The castor oil was prepared using the peroxyacetic acid by catalysis of phosphoric acid. Some factors which had effect on the epoxy value of product, such as reaction time, reaction temperature, the a- mounts of hydrogen peroxide etc were discussed. The result showed the effects of various parameters as follows：reaction time〉reaction temperature 〉 the amount of acid consumption〉 the amount of hydrogen peroxide 〉 catalyst concentration. FI-IPt was exploited to characterize the epoxidized castor oil, and then the differences of TG and DTG were compared to examine the thermal stability of epoxidized castor oil.

关 键 词：蓖麻油 环氧化反应 环氧化值 

分 类 号：TQ031.7[化学工程]