环辛四烯基稀土金属有机配合物  

Cyclooctatetraenyl Organolanthanide Complexes

作　　者：张立新[1] 周锡庚[1] 蔡瑞芳[1] 黄祖恩[1] 

机构地区：[1]复旦大学化学系,上海200433

出　　处：《有机化学》2000年第2期155-167,共13页Chinese Journal of Organic Chemistry

摘　　要：环辛四烯基稀土配合物是继茂基配合物之后的又一类非常重要的稀土金属有机配合物,本文将就这一领域的发展情况作一个简要的总结和回顾。The chemistry of cyclooctatetraenyl lanthanide complexes is currently receiving considerable attention. Many cyclooctatetraenyilanthanide complexes have been reported during the past several decades. The results show that cyclooctatetraenyl ligands with larger size and higher negative charges can often generate stable organolanthanide complexes of novel structures and unique properties. Herein is a brief review on the synthesis, structure and reactivity of these complexes.

关 键 词：稀土配合物 合成 结构 氧化还原法 配体交换法 

分 类 号：O641.4[理学—物理化学]