含金属簇Fe_3O手性配合物的合成与结构  

Synthesis and Structure of a Fe_3O Metal Cluster Chiral Complex

作　　者：刘阳[1] 周玄沐[1] 乔彬彬[1] 邓克俭[1] 

机构地区：[1]中南民族大学催化材料科学湖北省暨国家民委-教育部共建重点实验室,湖北武汉430074

出　　处：《广州化工》2012年第9期135-136,140,共3页GuangZhou Chemical Industry

摘　　要：以与L-脯氨酸(L-Pro)拓扑同构的手性配体L-半胱胺酸衍生物Lcys-(R)-噻唑啉-4-羧酸,与Fe(III)作用制得一种含金属簇Fe3O的手性配合物,通过X-射线单晶衍射测定并确认了其结构。A novel chiral L - cysteine derivative （R） - thiazolidine - 4 - carboxylic acid, which had a similar topolo- gical isomorphism with L - proline （ L - Pro）, was successfully prepared by raw material. A chiral complex containing metal cluster of Fe3 0 was prepared by the chiral ligand and Fe （III） metal ion, and the accurate crystal structure of this complex was determined and confirmed by X -ray diffraction.

关 键 词：手性 (R)-噻唑啉-4-羧酸 配合物 铁簇 

分 类 号：O611[理学—无机化学]