双亲性苯并咪唑类荧光化合物的合成及光谱性质研究  

Synthesis and spectrum properties of amphiphilic benzimidazole derivatives

作　　者：赵峙[1] 欧阳杰[1] 王秋生[1] 梁文睿[1] 王春颖[1] 赵欣[1] 曹磊[1] 王博威[1] 

机构地区：[1]天津理工大学化学化工学院,天津300384

出　　处：《天津理工大学学报》2012年第2期46-49,共4页Journal of Tianjin University of Technology

基　　金：国家自然科学基金青年科学基金(20903072);天津市自然科学基金(09JCYBJC05800)

摘　　要：通过引入烷基碳链和季铵盐结构,合成一种双亲性苯并咪唑类荧光化合物,对它的结构进行了表征,测定了Cu2+,Zn2+,K+,Mg2+,Al3+,Ca2+,Cd2+,Co2+,Hg2+,Mn2+,Na+,Fe3+对它的光谱性质的影响,发现Cu2+对这种化合物具有很好的荧光淬灭效果,而其它金属离子对它的荧光性质影响较小.此种化合物可作为一种选择性检测Cu2+的荧光传感器开展进一步的研究.In this paper,one of amphiphilic benzimidazole derivatives was synthesized by introducing the structure of carbon chain alkyl and quaternary ammonium salt.Its structure was characterized,and its variations of spectra with increasing concentrations of copper ion and other metal ions were measured.Spectra showed that there was a strong fluorescence destroy by increasing concentrations of copper ion,but there was not a strong fluorescence destroy by increasing other metal ions.So further research of this kind of compound as fluorescence sensor for copper ion can be made.

关 键 词：苯并咪唑 铜离子检测 荧光化合物 季铵盐 光谱性质 

分 类 号：O626[理学—有机化学]