PS-b-PnBA-OH的合成及对玻纤增强PS界面性能的影响  

Synthesis of Hydroxyl-Terminated Poly(n-Butylacrylate)-Block-Polystyrene and Its Effect on the Interface-Properties of Glass-Fiber/Polymer Composites

作　　者：申涛[1,2] 林群芳[2] 周晓东[1] 

机构地区：[1]华东理工大学化学工程联合国家重点实验室 [2]华东理工大学材料科学与工程学院,上海200237

出　　处：《高分子材料科学与工程》2012年第6期8-11,共4页Polymer Materials Science & Engineering

摘　　要：采用原子转移自由基聚合(ATRP)法合成了一系列羟基封端的两嵌段共聚物聚苯乙烯-b-聚丙烯酸丁酯(PS-b-Pn-BA-OH)。通过凝胶渗透色谱(GPC)、红外光谱(FT-IR)和核磁共振光谱等对合成产物进行了表征,并研究了其对玻璃基底材料表面性能和玻璃纤维/聚苯乙烯(GF/PS)复合材料界面剪切强度的影响。结果表明,羟基封端的嵌段聚合物对玻璃基底材料进行表面处理,可显著降低玻璃基底材料表面的亲水性;经过PS-b-PnBA-OH处理后,玻璃纤维/聚苯乙烯复合材料的界面剪切强度可以达到14.61MPa,是未处理的复合材料界面剪切强度的1.7倍左右。In this work,a series of hydroxyl-terminated poly（n-butylacrylate）-b-polystyrene（PS-b-PnBA-OH） were synthesized by atom transfer radical polymerization,and the molecular structures of the block polymers were characterized by FT-IR,1H-NMR and GPC.Then they were used as the macromolecular coupling agent for the improvement of the surface properties of glass substrates and the interface adhesion of glass fiber/PS composites.The results show that the hydrophily of glass substrates decreases significantly when the diblock copolymer is chemically anchored on the glass substrates.The interface shear strength of glass fiber/PS composites treated by the diblock polymers increases to 14.61 MPa,which is 1.7 times greater than the value of the untreated system.

关 键 词：嵌段聚合物 羟基封端 玻璃纤维 聚苯乙烯 界面 

分 类 号：TQ316.344[化学工程—高聚物工业]