2,2-二硝基丙醇最新合成进展及其应用  

Latest Synthesis Progress of 2,2-Dinitropropanol and Its Application

作　　者：朱天兵[1] 张寿忠[1] 刘长波[1] 马会强[1] 马英华[1] 苗成才[1] 

机构地区：[1]黎明化工研究院,河南洛阳471000

出　　处：《化学推进剂与高分子材料》2012年第3期32-36,42,共6页Chemical Propellants & Polymeric Materials

摘　　要：综述了氧化硝化法、氯化硝化法、铁氰化钾路线、电化学法等合成2,2–二硝基丙醇(DNPOH)的进展,并且比较了它们的特点,最后提出了洁净的电化学法是很有前途的绿色合成方法。另外,简述了DNPOH作为关键中间体在合成含能增塑剂和含能黏合剂中的应用情况。The progress in synthesis of 2,2-dinitropropanol （DNPOH） by oxidative nitrating method, chlorinating nitrating method, potassium ferricyanide route and electrochemical method is reviewed, and their characteristics are compared. At last, it is pointed out that the clean electrochemical method is a promising green synthesis method. In addition, the application situations of DNPOH as a key intermediate in synthesis of energetic plasticizers and binders are briefly described.

关 键 词：2 2-二硝基丙醇(DNPOH) 氧化硝化 铁氰化钾 电化学 含能材料 

分 类 号：TQ223.14[化学工程—有机化工]