环丁砜芳烃抽提蒸馏的计算机模拟  

Computer simulation of a process for extractive distillation of sulfolane aromatics

作　　者：霍月洋[1] 张树增[1] 

机构地区：[1]北京化工大学化学工程学院,北京100029

出　　处：《北京化工大学学报（自然科学版）》2012年第3期19-23,共5页Journal of Beijing University of Chemical Technology(Natural Science Edition)

摘　　要：根据文献报道的环丁砜-芳烃抽提体系相平衡数据,采用UNIFAC-Dortmund基团贡献模型拟合了CH2-SULF、ACH-SULF、ACCH2-SULF三对基团的交互作用参数;在此基础上运用流程模拟软件Aspen Plus对其工艺过程进行模拟研究分析。模拟计算结果表明各塔工艺操作参数与工业实际操作值基本吻合,抽余油中芳烃的质量分数为0.13%,苯产品收率达到99.95%,甲苯产品收率达到99.76%,芳烃纯度为99.89%,达到了工艺要求。Based on the phase equilibrium data sets of extraction systems for sulfolane aromatics reported in the literature,binary parameters for three pairs of groups（CH2-SULF,ACH-SULF and ACCH2-SULF） were found to regress well using the UNIFAC-Dortmund model.The process was subsequently simulated by Aspen Plus.The results of the simulation were well consistent with the industrial operating parameters.The content of aromatics in the raffinate was 0.13%,the recovery ratio of benzene was 99.95%,the toluene recovery ratio was 99.76%,and the purity of aromatics was 99.89%.

关 键 词：环丁砜 抽提蒸馏 UNIFAC-Dortmund模型 ASPEN Plus模拟 

分 类 号：TQ018[化学工程]