Synthesis and Crystal Structure of N-((6-chloropyridin-3-yl)methyl)-6-ethoxy-N-ethyl-3-nitropyridin-2-amine  

作　　者：吴道新 刘民华 柳爱平 黄明智 胡志彬 任叶果 刘兴平 唐明 左文清 

机构地区：[1]School of Chemistry and Biological Engineering,Changsha University of Science and Technology [2]National Engineering Research Center for Agrochemicals,Hunan Research Institute of Chemical Industry [3]College of Chemical Engineering,Xiangtan University

出　　处：《Chinese Journal of Structural Chemistry》2012年第5期621-624,共4页结构化学（英文）

基　　金：Supported by the National Basic Research Program of China (973 Program,2010CB126104);the NNSFC (Nos. 20572019 and 20872033);National Twelfth-five Key Project of China (Nos. 2011BAE06B01 and 2011BAE06B02);the NSF of Hunan Province (11JJ2006, 11JJ3022 and 10JJ3053);Science Plan of Hunan Province (2010FJ2003);research condition innovation of Hunan Province (2010PT2058)

摘　　要：The title compound N-（（6-chloropyridin-3-yl）methyl）-6-ethoxy-N-ethyl-3-nitropyri-din-2-amine（4） was synthesized by reacting the mixture of 6-chloro-2-ethoxy-3-nitropyridine（1） and 2-chloro-6-ethoxy-3-nitropyridine（2） with 3,and its structure was determined by X-ray single-crystal diffraction.The crystal belongs to the monoclinic system,space group P21/n with a = 7.3441（2）,b = 9.9041（3）,c = 11.7368（3） ,α = 101.410（2）,β = 102.1340（10）,γ = 99.594（2）o,μ = 0.260 mm^-1,Mr = 336.78,V = 798.58（4）（A°）^3,Z = 2,Dc = 1.401g/cm^3,F（000） = 352,T = 296（2） K,R = 0.0210 and wR = 0.1053.The title compound N-（（6-chloropyridin-3-yl）methyl）-6-ethoxy-N-ethyl-3-nitropyri-din-2-amine（4） was synthesized by reacting the mixture of 6-chloro-2-ethoxy-3-nitropyridine（1） and 2-chloro-6-ethoxy-3-nitropyridine（2） with 3,and its structure was determined by X-ray single-crystal diffraction.The crystal belongs to the monoclinic system,space group P21/n with a = 7.3441（2）,b = 9.9041（3）,c = 11.7368（3） ,α = 101.410（2）,β = 102.1340（10）,γ = 99.594（2）o,μ = 0.260 mm^-1,Mr = 336.78,V = 798.58（4）（A°）^3,Z = 2,Dc = 1.401g/cm^3,F（000） = 352,T = 296（2） K,R = 0.0210 and wR = 0.1053.

关 键 词：synthesis crystal structure N-（（6-chloropyridin-3-yl）methyl）-6-ethoxy-N-ethyl-3-nitropyridin-2-amine insecticidal and fungicidal activities 

分 类 号：O621.2[理学—有机化学]