Effect of cerium addition on catalytic performance of PtSnNa/ZSM-5 catalyst for propane dehydrogenation  

作　　者：Mengwei Xue Yuming Zhou Yiwei Zhang Xuan Liu Yongzheng Duan Xiaoli Sheng 

机构地区：[1]School of Chemistry and Chemical Engineering,Southeast University,Nanjing 211189,Jiangsu,China [2]School of Biochemical and Environmental Engineering,Nanjing Xiaozhuang University,Nanjing 211171,Jiangsu,China

出　　处：《Journal of Natural Gas Chemistry》2012年第3期324-331,共8页天然气化学杂志（英文版）

基　　金：supported by the National Natural Science Foundation of China (Grant No. 50873026 and 21106017);the Production and Research Prospective Joint Research Project of Jiangsu Province of China (Grant No. BY2009153);the Specialized Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20100092120047)

摘　　要：The effect of cerium addition on the catalytic performance of propane dehydrogenation over PtSnNaIZSM-5 catalyst has been investigated by reaction tests and some physicochemical characterization such as XRD, BET, TEM, XPS, NH3-TPD, H2 chemisorption, TPR and TPO techniques. It has been found that with suitable amount of cerium addition, the platinum dispersion increased, while the carbon deposition tended to be eliminated easily. In these cases, the presence of cerium could not only realize the better distribution of metallic particles on the support, but also strengthen the interactions between Sn species and the support. Additionally, XPS spectra confirmed that more amounts of tin could exist in oxidized form, which was advantageous to the reaction. In our experiments, PtSnNaCe （1.1 wt%）/ZSM-5 catalyst exhibited the best catalytic performance. After running the reaction for 750 h, propane conversion was maintained higher than 30% with the corresponding selectivity to propylene of about 97%.The effect of cerium addition on the catalytic performance of propane dehydrogenation over PtSnNaIZSM-5 catalyst has been investigated by reaction tests and some physicochemical characterization such as XRD, BET, TEM, XPS, NH3-TPD, H2 chemisorption, TPR and TPO techniques. It has been found that with suitable amount of cerium addition, the platinum dispersion increased, while the carbon deposition tended to be eliminated easily. In these cases, the presence of cerium could not only realize the better distribution of metallic particles on the support, but also strengthen the interactions between Sn species and the support. Additionally, XPS spectra confirmed that more amounts of tin could exist in oxidized form, which was advantageous to the reaction. In our experiments, PtSnNaCe （1.1 wt%）/ZSM-5 catalyst exhibited the best catalytic performance. After running the reaction for 750 h, propane conversion was maintained higher than 30% with the corresponding selectivity to propylene of about 97%.

关 键 词：CERIUM Pt-Sn propane dehydrogenation CATALYST 

分 类 号：TQ221.212[化学工程—有机化工] O643.36[理学—物理化学]