Highly Efficient Organic Ultraviolet Photodetectors Based on Re(I) Complexes  

作　　者：LIU Chun-bo WANG Long LIU Min LI Chuan-bi LI Chun-mei CHE Guang-bo SU Bin 

机构地区：[1]College of Chemistry,Jilin Normal University,Siping 136000,P.R.China [2]College of Environmental Engineering,Jilin Normal University,Siping 136000,P.R.China

出　　处：《Chemical Research in Chinese Universities》2012年第3期503-506,共4页高等学校化学研究（英文版）

基　　金：Supported by the National Natural Science Foundation of China(No.60978059);the Program for New Century Excellent Talents in Universities of China(No.NCET-10-0176);the Key Project of Ministry of Education of China(No.210053);the Natural Science Foundation of Jilin Province,China(Nos.20101543 and 20100549)

摘　　要：High response organic ultraviolet photodetectors（UV-PDs） were demonstrated with 4,4＇,4”- tris[3-methyl-pheny（phenyl）amino]triphenylamine（m-MTDATA） and two Re（Ⅰ） complexes, （bathocuproine）- Re（CO）3CI（Re-BCP） and （bathophenanthroline）Re（CO）3Cl（Re-Bphen） to act as the electron donor and acceptor, re- spectively. UV-PDs have the configuration of indium tin oxide（ITO）/m-MTDATA（25 nm）/m-MTDATA：Re-complex （25-35 nm）/Re-complex（20 nm）/LiF（l nm）/Al（200 nm） with different blend layer thicknesses of 25, 30 and 35 nm. The optimized PD based on Re-Bphen offers a corrected-dark photocurrent up to 760μA/cm^2 at -10 V, corresponding to a response of 310 mA/W which is among the best values reported for organic UV-PDs. Excellent electron transport ability makes for such high photo-to-electron conversion.High response organic ultraviolet photodetectors（UV-PDs） were demonstrated with 4,4＇,4”- tris[3-methyl-pheny（phenyl）amino]triphenylamine（m-MTDATA） and two Re（Ⅰ） complexes, （bathocuproine）- Re（CO）3CI（Re-BCP） and （bathophenanthroline）Re（CO）3Cl（Re-Bphen） to act as the electron donor and acceptor, re- spectively. UV-PDs have the configuration of indium tin oxide（ITO）/m-MTDATA（25 nm）/m-MTDATA：Re-complex （25-35 nm）/Re-complex（20 nm）/LiF（l nm）/Al（200 nm） with different blend layer thicknesses of 25, 30 and 35 nm. The optimized PD based on Re-Bphen offers a corrected-dark photocurrent up to 760μA/cm^2 at -10 V, corresponding to a response of 310 mA/W which is among the best values reported for organic UV-PDs. Excellent electron transport ability makes for such high photo-to-electron conversion.

关 键 词：Organic ultraviolet photodetector Re（Ⅰ） complex High electron transport ability 

分 类 号：TN23[电子电信—物理电子学] S858.305.3[农业科学—临床兽医学]