Solvothermal preparation of iron phosphonate cages  

作　　者：WINPENNY Richard E. P. 

机构地区：[1]School of Chemistry, University of Manchester, Manchester M13 9PL, United Kingdom [2]The Photon Science Institute, University of Manchester, Manchester M13 9PL, United Kingdom

出　　处：《Science China Chemistry》2012年第6期910-913,共4页中国科学（化学英文版）

基　　金：financially supported by Marie Curie International Incoming Fellowship (E.C. Contract No: PIIF-GA-2008-219588);the starting fund of Xi’an Jiaotong University (to YZZ);the Engineering and Physical Science Research Council (UK);the Royal Society for a Wolfson Merit Award (to REPW)

摘　　要：Three new iron（Ⅲ） phosphonate cage-like complexes with [Fe4], [Feg] and [Fe14] cores have been synthesized by solvothermal reaction with various starting materials. Magnetic studies show overall antiferromagnetic interaction presented in these cages.Three new iron(Ⅲ) phosphonate cage-like complexes with [Fe 4 ], [Fe 9 ] and [Fe 14 ] cores have been synthesized by solvothermal reaction with various starting materials. Magnetic studies show overall antiferromagnetic interaction presented in these cages.

关 键 词：POLYNUCLEAR IRON coordination PHOSPHONATE magnetic properties 

分 类 号：O641.4[理学—物理化学]