Cyanide-bridged W~ⅤMn~Ⅲ single-chain magnet based on an octacoordinate [W(CN)_6(phen)]^- anion  

作　　者：LEE JinWuk LIM KwangSoo YOON JungHee RYU DaeWon KOO BongHo KOH EuiKwan HONG ChangSeop 

机构地区：[1]Department of Chemistry, Research Institute for Natural Sciences, Korea University, Seoul 136-713, Korea [2]Nano-Bio System Research Team, Korea Basic Science Institute, Seoul 136-713, Korea

出　　处：《Science China Chemistry》2012年第6期1012-1017,共6页中国科学（化学英文版）

基　　金：supported by the National Research Foundation of Korea Funded by the Korean Government (2011-0003264);by the Priority Research Centers Program through the National Research Foundation of Korea (NRF) Funded by the Ministry of Education, Science and Technology (NRF20110018396)

摘　　要：Reaction of unique [W（CN）6（phen）]- with a magnetically anisotropic Mn Schiff base yielded a wv（5d）-Mnm（3d） bimetallic compound with a linear chain structure. The magnetic properties of the chain complex feature a ferrimagnetic behavior as well as slow magnetic relaxation typical for a single-chain magnet.Reaction of unique [W(CN)6(phen)]- with a magnetically anisotropic Mn Schiff base yielded a WⅤ(5d)-MnⅢ(3d) bimetallic compound with a linear chain structure. The magnetic properties of the chain complex feature a ferrimagnetic behavior as well as slow magnetic relaxation typical for a single-chain magnet.

关 键 词：tungsten MANGANESE CYANIDE crystal structure single-chain magnet 

分 类 号：O611.3[理学—无机化学]