Microwave absorbing properties of NdFeCo magnetic powder  

作　　者：王磊 林培豪 潘顺康 周怀营 

机构地区：[1]Guangxi Key Laboratory of Information Materials,Guilin University of Electronic Technology

出　　处：《Journal of Rare Earths》2012年第6期529-533,共5页稀土学报（英文版）

基　　金：National Natural Science Foundation of China(50961005);Natural Science Foundation of Guangxi(0991002Z);Innovation Project of Guangxi Graduate Education(2011105950805M38)

摘　　要：NdFeCo magnetic powder was prepared by the process of smelting, high-energy ball milling and oxidation heat treating. The effects of oxidation heat treatment and Co content on phase composition and microwave absorbing properties of NdFeCo magnetic powder were investigated by an X-ray diffractometer （XRD） and vector network analyzer. The minimum reflectivity of Nd23.25Fe36.75Co40 powder before oxidation heat treatment was 4.2 dB, and that of oxidized powder decreased to -14.0 dB. The microwave absorbing properties of NdFeCo magnetic powder could be improved effectively by oxidation heat treatment. With the increase of Co content, the Fe2O3 reduced and the Nd2O3 increased; Fe3CO7 phase appeared when the content of Co increased to 40% （mass ratio）; the absorption peak was found to move towards lower frequency region first, and then it moved towards a higher frequency region. Nd23.25Fe06.75Co10 powder had better comprehensive properties in absorbing microwave in the frequency band of 3-13 GHz. The value of minimum reflectivity and absorption peak frequency, when the coating thickness （d） was 1.8 mm, were -19.7 dB and 4.8 GHz, respectively.NdFeCo magnetic powder was prepared by the process of smelting, high-energy ball milling and oxidation heat treating. The effects of oxidation heat treatment and Co content on phase composition and microwave absorbing properties of NdFeCo magnetic powder were investigated by an X-ray diffractometer （XRD） and vector network analyzer. The minimum reflectivity of Nd23.25Fe36.75Co40 powder before oxidation heat treatment was 4.2 dB, and that of oxidized powder decreased to -14.0 dB. The microwave absorbing properties of NdFeCo magnetic powder could be improved effectively by oxidation heat treatment. With the increase of Co content, the Fe2O3 reduced and the Nd2O3 increased; Fe3CO7 phase appeared when the content of Co increased to 40% （mass ratio）; the absorption peak was found to move towards lower frequency region first, and then it moved towards a higher frequency region. Nd23.25Fe06.75Co10 powder had better comprehensive properties in absorbing microwave in the frequency band of 3-13 GHz. The value of minimum reflectivity and absorption peak frequency, when the coating thickness （d） was 1.8 mm, were -19.7 dB and 4.8 GHz, respectively.

关 键 词：NdFeCo absorbing property oxidation heat treatment rare earths 

分 类 号：O614.33[理学—无机化学]