共价双金属配合物在分子导线方面的研究进展  

Progress on Bimetallic Complex as Molecular Wires

作　　者：韩美娟[1] 

机构地区：[1]同济大学化学系,上海200092

出　　处：《化学通报》2012年第6期496-501,共6页Chemistry

摘　　要：共价双金属配合物因其结构的优越性,在分子器件特别是分子导线的研究方面有广阔的应用前景。分子内电子耦合作用的研究是揭示这类配合物构成的分子导线性能的关键之一。本文介绍了共价双金属配合物的分子内电子耦合作用及此类配合物的结构特点,总结了近年来共价双金属配合物在分子导线领域的研究进展,并对共价双金属配合物的发展前景进行了展望。Covalently linked bimetallic complexes with unique properties show broad application prospects in the field of molecular device,especially as molecular wires.The intramolecular electronic coupling investigation of these complexes plays crucial role in disclosing the properties of molecular devices.In this article,the electronic coupling and structure properties of the bimetallic complexes were introduced,and the recent progress of bimetallic complexes as molecular wires and the perspective of this field were summarized.

关 键 词：共价双金属配合物 分子内电子耦合作用 分子导线 

分 类 号：O641.4[理学—物理化学]