氮杂环丙烷与双键化合物的[3+2]环加成反应研究进展  

The Research Progress in the Cycloaddition of Azirdines and Compounds with Double Bond

作　　者：魏文珑[1] 倪斌[1] 李兴[1] 常宏宏[1] 

机构地区：[1]太原理工大学化学化工学院,山西太原030024

出　　处：《化工时刊》2012年第6期51-55,共5页Chemical Industry Times

摘　　要：咪唑烷、恶唑烷和吡咯烷等五元氮杂环在有机合成的应用十分广泛,而氮杂环丙烷与不饱和双键化合物的[3+2]环加成反应是合成此类化合物的一种便捷高效的方法。综述了近年来氮杂环丙烷与亚胺、烯烃、醛酮等含有双键化合物的[3+2]环加成反应研究进展,并对其发展方向进行了展望。Five- membered nitrogen containing oxaza heterocyclic such as Imidazolidine, Oxazolidine, Pyrroli- dine, have broad application in Organic Syntheses. The [ 3 ＋ 2 ] cycloaddition of azirdines and double bond com- pounds was a efficient and convenient route. The research of the [ 3 ＋ 2 ] cycloaddition of azirdines and compounds with double bond, for instance, imine, alkene, aldehyde and ketone, was reviewed and the developing prospects was also discussed.

关 键 词：氮杂环丙烷 双键化合物 [3+2]环加成反应 研究进展 

分 类 号：O621.25[理学—有机化学]