Effect of cationic monomer on properties of fluorinated acrylate latex  

作　　者：Li Jun Chen 

机构地区：[1]School of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032, China

出　　处：《Chinese Chemical Letters》2012年第6期736-740,共5页中国化学快报（英文版）

基　　金：supported by the Science and Technology Department of Zhejiang Province under Grant No. 2010C31040;the financial support of Zhejiang Provincial Natural Science Foundation of China(No. Y4100152);Zhejiang University of Technology Natural Science Foundation(No.20100202)

摘　　要：Cationic fluorinated acrylate latex was prepared via semi-continuous emulsion copolymerization of cationic monomer and other monomers. The resultant latex and its film were characterized with dynamic light scattering detector and contact angle meter. Influences of amount of DMDAAC on the properties of resultant latex and its film were investigated in detail. Results show that the particle size of the latex has the minimum value knd the zeta potential of the latex is increased when the amount of DMDAAC is increased. In addition, the particle size of the latex is unimodal distribution when the amount of DMDAAC is not more than 2.5%. However, the particle size of the latex is bimodal distribution when the amount of DMDAAC is more than 2.5%. The contact angle is varied slightly with the increase of amount of DMDAAC when it is not more than 2.5%. Nevertheless, the contact angle is decreased with the increase of the amount of DMDAAC when it is more than 2.5%.Cationic fluorinated acrylate latex was prepared via semi-continuous emulsion copolymerization of cationic monomer and other monomers. The resultant latex and its film were characterized with dynamic light scattering detector and contact angle meter. Influences of amount of DMDAAC on the properties of resultant latex and its film were investigated in detail. Results show that the particle size of the latex has the minimum value knd the zeta potential of the latex is increased when the amount of DMDAAC is increased. In addition, the particle size of the latex is unimodal distribution when the amount of DMDAAC is not more than 2.5%. However, the particle size of the latex is bimodal distribution when the amount of DMDAAC is more than 2.5%. The contact angle is varied slightly with the increase of amount of DMDAAC when it is not more than 2.5%. Nevertheless, the contact angle is decreased with the increase of the amount of DMDAAC when it is more than 2.5%.

关 键 词：Cationic fluorinated acrylate latex Cationic monomer Semi-continuous emulsion polymerization PROPERTIES 

分 类 号：TQ325.7[化学工程—合成树脂塑料工业] TS727.2[轻工技术与工程—制浆造纸工程]