中位-四(对烷氧苯基 )卟啉 Co^(2+)、Cu^(2+)、Zn^(2+)、Pb^(2+)配合物的合成与表征  

Synthesis and Structure Identification of Complexes of meso-Tetrakis (4-alkoxyphenyl )Porphyrins with Co^(2+), Cu^(2+),Zn^(2+), Pb^(2+)

作　　者：赵鸿斌[1] 蔡剑[1] 林原斌[1] 罗志强[1] 刘键[1] 宁静恒[1] 周尽花[1] 

机构地区：[1]湘潭大学化学化工学院,湘潭411105

出　　处：《无机化学学报》2000年第3期515-518,共4页Chinese Journal of Inorganic Chemistry

基　　金：湖南省教委资助项目

摘　　要：Synthesis of fourteen new complexes of meso-tetrakis（4-alkoxyphenyl） porphyrins with Co2+, Cu2+, Zn2+, Pb2+ were presented in this paper. Meso-tetrakis （4-alkoxyphenyl） porphyrins were prepared by condensation of 4-alkoxybenzaldehydes with pyrrole, then treated with corresponding metallic acetate to produce mentioned complexes, IR, UV, 1H NMR, MS and elementary analysis were explored to confirm the structures of all theses new complexes. Characteristic spectrometric data of IR, UV, 1H NMR related to these complexes have been systematically summarized. Ten of the fourteen complexes were found to exhibit liquid crystal properties.Synthesis of fourteen new complexes of meso-tetrakis(4-alkoxyphenyl) porphyrins with Co^(2+), Cu^(2+), Zn^(2+), Pb^(2+) were presented in this paper. Meso-tetrakis (4-alkoxyphenyl) porphyrins were prepared by condensation of 4-alkoxybenzaldehydes with pyrrole, then treated with corresponding metallic acetate to produce mentioned complexes, IR, UV, ~1H NMR, MS and elementary analysis were explored to confirm the structures of all theses new complexes. Characteristic spectrometric data of IR, UV, ~1H NMR related to these complexes have been systematically summarized. Ten of the fourteen complexes were found to exhibit liquid crystal properties.

关 键 词：中位-四(对烷氧苯基)卟啉 金属配合物 合成 

分 类 号：O626.13[理学—有机化学] O614[理学—化学]