壳聚糖膜固定化双水杨叉乙二胺合钴的合成与表征  

Synthesis and Characterazation of Co (Ⅱ) Complex of Bis(Salicylideneethylene Diamine) Immobilized to Chitosan

作　　者：胡道道[1] 史启祯[1] 唐宗薰[1] 房喻[2] 

机构地区：[1]西北大学化学系,西安710069 [2]陕西师范大学化学系,西安710062

出　　处：《无机化学学报》2000年第3期535-539,共5页Chinese Journal of Inorganic Chemistry

基　　金：陕西省自然科学基金!(No.98H02);南京大学配位化学国家重点实验室资助

摘　　要：A cobalt complex, Co (Ⅱ) complex of his(salicylideneethylene diamine, Cosalen) immobilized to chitosan film was prepared. It was instrumentally characterized by elemental analyses, IR, UV-VIS, XPS and ESR spectroscopy. It was demonstrated that the immobilization of Cosalen was realized through the coordination of the amino group in Chitosan with the Co (Ⅱ) in the CoSalen complex. It binds molecular oxygen reversibly in the solid state through the vacant sixth coordination site.A cobalt complex, Co (Ⅱ) complex of his(salicylideneethylene diamine, Cosalen) immobilized to chitosan film was prepared. It was instrumentally characterized by elemental analyses, IR, UV-VIS, XPS and ESR spectroscopy. It was demonstrated that the immobilization of Cosalen was realized through the coordination of the amino group in Chitosan with the Co (Ⅱ) in the CoSalen complex. It binds molecular oxygen reversibly in the solid state through the vacant sixth coordination site.

关 键 词：壳聚糖 双水杨叉乙二胺合钴 固定化配合物 合成 

分 类 号：O614.812[理学—无机化学]