脉冲激光溅射合成全氯代多环芳烃  

Synthesis of Perchlorinated Polycyclic Aromatic Hydrocarbon by Laser Ablation

作　　者：周异男[1] 谢素原[1] 陈宏[1] 黄荣彬[1] 郑兰荪[1] 

机构地区：[1]厦门大学化学系固体表面物理化学国家重点实验室,厦门361005

出　　处：《高等学校化学学报》2000年第5期789-790,共2页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金!(批准号:29890210)

摘　　要：By laser ablating graphite in the vapor of tetrachloromethane, a series of perchlorinated polycyclic aromatic hydrocarbons were synthesized. Among them, hexachlorobenzene (C6Cl6), octachloronaphthalene (C10 Cl8), octachloroacenaphthylene (C12 Cl8), decachloroanthracene (C14 Cl10), decachlorophenanthrene (C14 Cl10 ), decachloropyrene (C16 Cl10 ), decachlorofluoranthene (C16Cl10 ), C18 Cl10, C20Cl10, C22Cl12 and C24Cl12 were identified by HPLC-UV-MS. The results demonstrate the potential of the reaction for synthesizing the compounds with special structures.By laser ablating graphite in the vapor of tetrachloromethane, a series of perchlorinated polycyclic aromatic hydrocarbons were synthesized. Among them, hexachlorobenzene (C6Cl6), octachloronaphthalene (C10 Cl8), octachloroacenaphthylene (C12 Cl8), decachloroanthracene (C14 Cl10), decachlorophenanthrene (C14 Cl10 ), decachloropyrene (C16 Cl10 ), decachlorofluoranthene (C16Cl10 ), C18 Cl10, C20Cl10, C22Cl12 and C24Cl12 were identified by HPLC-UV-MS. The results demonstrate the potential of the reaction for synthesizing the compounds with special structures.

关 键 词：脉冲激光溅射 合成 全氯代多环芳烃 

分 类 号：O625.2[理学—有机化学] O644.18[理学—化学]