α-蒎烯氧化中的催化作用研究进展  

Investigation on the Catalysis in the Oxidation of α-Pinene

作　　者：郑敏[1] 何必飞[2] 俆琼 尹笃林[2] 

机构地区：[1]湖南第一师范学院,湖南长沙410205 [2]化学生物学及中药分析教育部重点实验室,湖南师范大学精细催化合成研究所,湖南长沙410081

出　　处：《林产化学与工业》2012年第3期126-130,共5页Chemistry and Industry of Forest Products

基　　金：国家自然科学基金资助项目(20572021,21003043);湖南第一师范学院项目(XYS10N04)

摘　　要：概述了近20年来国内外对催化α-蒎烯氧化反应过程的研究,重点分析了α-蒎烯氧化中催化剂的性能特点及产物分布规律,总结了过渡金属盐、氧化物、配合物、分子筛及杂多酸在α-蒎烯氧化中的催化作用,比较了催化活性及选择性的特点,并初步探讨了发展趋势。提出在已有的α-蒎烯氧化反应催化剂中,分子筛类催化剂在制备方法和工业化发展上有一定的优势,深入研究过渡金属化合物在α-蒎烯氧化反应的催化性能及调变方法,应是α-蒎烯氧化反应中值得重点关注的研究内容。The catalysis in the oxidation of α-pinene during the last two decades was reviewed. The catalysis of transition-metal salts, oxides, coordination compounds, zeolites and heteropoly acids for the reactions were presented. The activity and selectivity of these catalysts were compared. It is emphasized that the innovation in the catalytic oxidation of α-pinene should be focused on improving the atom economy. The catalytic properties and modifications of transition-metal compounds for the reaction should be deeply investigated. The development of industrial equipments and processes should be concerned.

关 键 词：Α-蒎烯 催化剂 氧化反应 

分 类 号：TQ35[化学工程]