芴酮引发光接枝改性LDPE膜的研究  

SURFACE PHOTOGRAFTING OF FUNCTIONAL MONOMERS INITIATED BY FLUORENONE ON LDPE FILMS

作　　者：席改卿[1,2] 尹梅贞[2] 杨万泰[2] 

机构地区：[1]邯郸学院化学系,邯郸056005 [2]北京化工大学材料科学与工程学院,北京100029

出　　处：《高分子学报》2012年第7期784-788,共5页Acta Polymerica Sinica

基　　金：国家自然科学基金重点项目(基金号51033001);北京市共建项目专项资助;中央高校基本科研业务费(项目号ZZ1208);国家高技术研究发展计划(863计划;项目号2009AA03Z325)资助

摘　　要：采用紫外光引发接枝表面改性的方法,以芴酮(FL)为引发剂,在低密度聚乙烯(LDPE)薄膜表面上接枝丙烯酸(AA)、甲基丙烯酸(MAA)、丙烯酸甲酯(MA)、甲基丙烯酸甲酯(MMA)、丙烯酰胺(AM)等单体,以赋予薄膜表面新的化学性质.考察了引发剂浓度、紫外光的辐照时间、辐照强度、单体种类对LDPE薄膜接枝程度的影响.结果表明,在一定范围内,增加芴酮浓度,可以提高单体的接枝率,但当芴酮浓度达到5%时,接枝率反而下降.延长辐照时间至4 min和提高紫外光的辐照强度达100 W/m2,均有利于接枝反应的进行.不同单体在LDPE膜上的接枝能力与单体的活性、单体与基材的相容性等因素有关.接枝后,LDPE与水的接触角下降程度不仅与单体在膜上的接枝量有关,还与接枝单体的亲水性能密切相关.Via the process of photografting surface modification by UV light,fluorenone （FL） was employed as an initiator in the grafting reaction of acrylic acid （AA） , acryamide （AM） , methylaerylie acid （MAA） , methyl acrylate （MA） and methyl methacrylate （MMA） onto the surface of LDPE films for introducing newchemical properties to the film surface. In this study, influences of the initiator concentration, UV light irradiation time, UV light irradiation intensity as well as the types of functional monomers on the grafting yield of LDPE films were investigated respectively. Within a certain range, the results showed that raising the fluorenone concentration would lead to the increasing of the grafting yield, however, when the fluorenone concentration reached 5% , the grafting yield decreased. The grafting polymerization was fully promoted by increasing the light irradiation intensity up to 100 W/m2 and prolonging the UV light irradiation time to 4 min. Grafting ability of different types of monomers on LDPE films was concerned with parameters such as activity ofmonomers, compatibility of monomers with the matrix and so on. After successful monomers,the changes of water contact angle of the grafted LDPE film were related monomer on the film as well as the hydrophilicity of the applied monomers. grafting of functional to the grafting yield of

关 键 词：芴酮 紫外光表面接枝 低密度聚乙烯薄膜 接枝率 接触角 

分 类 号：TQ320.721[化学工程—合成树脂塑料工业]