分子筛在加氢脱硫催化剂深度脱硫方面的应用  

Application of Zeolites in Hydrodesulfurization Catalysts for Deep Desulfurization

作　　者：尹海亮[1] 周同娜 柴永明[3] 柳云骐[3] 刘晨光[3] 

机构地区：[1]中国石油大学(华东)重质油国家实验室科学技术研究院,东营257061 [2]东营市环境保护局,东营257300 [3]中国石油大学(华东)重质油国家实验室,青岛266555

出　　处：《化学进展》2012年第7期1252-1261,共10页Progress in Chemistry

基　　金：国家重点基础研究发展计划(973)项目(No.2010CB226905)资助

摘　　要：本文综述了分子筛对加氢脱硫催化剂深度脱硫性能的影响,对分子筛基加氢脱硫催化剂上涉及含硫大分子4,6-二甲基二苯并噻吩(4,6-DMDBT)加氢脱硫反应的研究进展作了总结。主要介绍了微孔分子筛、介孔分子筛、微介孔复合分子筛和纳米分子筛在加氢脱硫催化剂针对4,6-DMDBT加氢脱硫反应方面的应用进展。简要介绍了分子筛基加氢脱硫催化剂上4,6-DMDBT加氢脱硫反应的反应途径、反应机理及抑制过度裂化反应的措施。最后展望了该研究领域的发展前景。The recent progress in the application of zeolites in hydrodesulfurization catalysts for the deep desulfurization is reviewed in this paper, including microporous zeolite, mesoporous zeolite, micro-mesoporous zeolite and nano-zeolite. The reaction pathways and mechanisms of the hydrodesulfurization of 4,6-DMDBT and the measures to inhibit the overcracking reactions of desulfurization products over hydrodesulfurization catalysts containing zeolites are described briefly. Finally, challenges and prospects for further development of this field are presented.

关 键 词：分子筛 4 6-二甲基二苯并噻吩 加氢脱硫 

分 类 号：O643.3[理学—物理化学]