Shellac-coated iron oxide nanoparticles for removal of cadmium(Ⅱ) ions from aqueous solution  

作　　者：Jilai Gong Long Chen Guangming Zeng Fei Long Jiuhua Deng Qiuya Niu Xun He 

机构地区：[1]College of Environmental Science and Engineering,Hunan University,Changsha 410082,China [2]Key Laboratory of Environmental Biology and Pollution Control,Hunan University,Ministry of Education,Changsha 410082,China [3]State Key Laboratory of Chemo/Bioensing and Chemometrics,Hunan University,Changsha 410082,China

出　　处：《Journal of Environmental Sciences》2012年第7期1165-1173,共9页环境科学学报（英文版）

基　　金：supported by the National Natural Science Foundation of China (No. 50808070, 51039001);the Program for New Century Excellent Talents in University from the Ministry of Education of China (No. NCET-09-0328);the Postdoctoral Science Foundation of China (No.20070410301, 200902468);the Program for Changjiang Scholars and Innovative Research Team in University(No. IRT0719);the Hunan Provincial Natural Science Foundation of China (No. 08JJ4006, 10JJ7005);the Xiangjiang Water Environmental Pollution Control Project subjected to the National Key Science and Technology Project for Water Environmental Pollution Control (No.2009ZX07212-001-02, 2009ZX07212-001-06);the Hunan Key Scientific Research Project (No. 2009FJ1010)

摘　　要：This study describes a new effective adsorbent for cadmium removal from aqueous solution synthesized by coating a shellac layer, a natural biodegradable and renewable resin with abundant hydroxyl and carboxylic groups, on the surface of iron oxide magnetic nanoparticles. Transmission Electron Microscopy （TEM） imaging showed shellac-coated magnetic nanoparticle （SCMN） adsorbents had a core-shell structure with a core of 20 nm and shell of 5 nm. Fourier Transform Infrared Spectroscopic analysis suggested the occurrence of reaction between carboxyl groups on the SCMN adsorbent surface and cadmium ions in aqueous solution. Kinetic data were well described by pseudo second-order model and adsorption isotherms were fitted with both Langmuir and Freundlich models with maximum adsorption capacity of 18.80 mg]g. SCMN adsorbents provided a favorable adsorption capacity under high salinity conditions, and cadmium could easily be desorbed using mild organic acid solutions at low concentration.This study describes a new effective adsorbent for cadmium removal from aqueous solution synthesized by coating a shellac layer, a natural biodegradable and renewable resin with abundant hydroxyl and carboxylic groups, on the surface of iron oxide magnetic nanoparticles. Transmission Electron Microscopy （TEM） imaging showed shellac-coated magnetic nanoparticle （SCMN） adsorbents had a core-shell structure with a core of 20 nm and shell of 5 nm. Fourier Transform Infrared Spectroscopic analysis suggested the occurrence of reaction between carboxyl groups on the SCMN adsorbent surface and cadmium ions in aqueous solution. Kinetic data were well described by pseudo second-order model and adsorption isotherms were fitted with both Langmuir and Freundlich models with maximum adsorption capacity of 18.80 mg]g. SCMN adsorbents provided a favorable adsorption capacity under high salinity conditions, and cadmium could easily be desorbed using mild organic acid solutions at low concentration.

关 键 词：cadmium ions SHELLAC iron oxide nanoparticles natural material magnetic separation 

分 类 号：O647.2[理学—物理化学] O614.811[理学—化学]