A novel colorimetric method for field arsenic speciation analysis  

作　　者：Shan Hu Jinsuo Lu Chuanyong Jing 

机构地区：[1]State Key Laboratory of Environmental Chemistry and Ecotoxicology,Research Center for Eco-Environmental Sciences,Chinese Academy of Sciences,Beijing 100085,China [2]School of Environmental and Municipal Engineering,Xi'an University of Architecture and Technology,Xi'an 710055,China

出　　处：《Journal of Environmental Sciences》2012年第7期1341-1346,共6页环境科学学报（英文版）

基　　金：the financial support of the National Natural Science Foundation of China (No. 20977098,20921063);the National Basic Research Program (973) of China (No. 2010CB933502)

摘　　要：Accurate on-site determination of arsenic （As） concentration as well as its speciation presents a great environmental challenge especially to developing countries. To meet the need of routine field monitoring, we developed a rapid colorimetric method with a wide dynamic detection range and high precision. The novel application of KMnO4 and CHaN2S as effective As（III） oxidant and As（V） reductant, respectively, in the formation of molybdenum blue complexes enabled the differentiation of As（III） and As（V）. The detection limit of the method was 8 ~tg/L with a linear range （R2 = 0.998） of four orders of magnitude in total As concentrations. The As speciation in groundwater samples determined with the colorimetric method in the field were consistent with the results using the high performance liquid chromatography atomic fluorescence spectrometry, as evidenced by a linear correlation in paired analysis with a slope of 0.9990- 0.9997 （p 〈 0.0001, n = 28）. The recovery of 96%-116% for total As, 85%-122% for As（III）, and 88%-127% for As（V） were achieved for groundwater samples with a total As concentration range 100-800 μg/L. The colorimetric result showed that 3.61 g/L As（III） existed as the only As species in a real industrial wastewater, which was in good agreement with the HPLC-AFS result of 3.56 g/L As（Ⅲ）. No interference with the color development was observed in the presence of sulfate, phosphate, silicate, humic acid, and heavy metals from complex water matrix. This accurate, sensitive, and easy-to-use method is especially suitable for field As determination.Accurate on-site determination of arsenic （As） concentration as well as its speciation presents a great environmental challenge especially to developing countries. To meet the need of routine field monitoring, we developed a rapid colorimetric method with a wide dynamic detection range and high precision. The novel application of KMnO4 and CHaN2S as effective As（III） oxidant and As（V） reductant, respectively, in the formation of molybdenum blue complexes enabled the differentiation of As（III） and As（V）. The detection limit of the method was 8 ~tg/L with a linear range （R2 = 0.998） of four orders of magnitude in total As concentrations. The As speciation in groundwater samples determined with the colorimetric method in the field were consistent with the results using the high performance liquid chromatography atomic fluorescence spectrometry, as evidenced by a linear correlation in paired analysis with a slope of 0.9990- 0.9997 （p 〈 0.0001, n = 28）. The recovery of 96%-116% for total As, 85%-122% for As（III）, and 88%-127% for As（V） were achieved for groundwater samples with a total As concentration range 100-800 μg/L. The colorimetric result showed that 3.61 g/L As（III） existed as the only As species in a real industrial wastewater, which was in good agreement with the HPLC-AFS result of 3.56 g/L As（Ⅲ）. No interference with the color development was observed in the presence of sulfate, phosphate, silicate, humic acid, and heavy metals from complex water matrix. This accurate, sensitive, and easy-to-use method is especially suitable for field As determination.

关 键 词：arsenic speciation colorimetric method GROUNDWATER field analysis 

分 类 号：O657.31[理学—分析化学] TS227[理学—化学]