同步辐射光电离质谱法研究卷烟主流烟气气相成分  

Analysis of Gas Phase Components in Mainstream Cigarette Smoke with Synchrotron Radiation Photoionization Mass Spectrometry

作　　者：王健[1,2] 翁俊桀[2] 贾良元[2] 潘洋[2] 

机构地区：[1]上海烟草集团有限责任公司技术中心,上海200082 [2]中国科学技术大学国家同步辐射实验室,合肥230029

出　　处：《分析化学》2012年第7期1048-1052,共5页Chinese Journal of Analytical Chemistry

基　　金：烟草行业卷烟烟气重点实验室开放研究基金(No.2010-00539);国家自然科学基金(No.11175185)资助项目

摘　　要：利用同步辐射光电离质谱法对卷烟主流烟气气相成分进行了研究。首先,利用针筒捕集主流烟气气相成分,在未进行样品处理和分离的情况下,实时、在线获得烟气的光电离质谱图;再扫描光电离效率(PIE)谱,获得气相成分的电离能(IE),并对其进行归属;最后,以商用吸烟机对卷烟进行抽吸,获得单口烟气中甲醇、乙炔等化学成分相对含量随抽吸口数增加的变化情况,并探讨了可能原因。The gas-phase components in the mainstream cigarette smoke have been investigated by synchrotron radiation photoionization mass spectrometry. First, the smoke was trapped by a modified syringe. Photoionization mass spectra for the smoke were obtained directly on-line, without pretreatment and separation. Second, ionization energies fIE） of the components at each m/z were obtained by scanning the photoionization efficiency （PIE） spectra. Possible components could be assigned by comparing the experimental IE with known data. Final, the puff-by-puff behaviors of some components were studied using a commercial smoking machine.

关 键 词：同步辐射 光电离 质谱 主流烟气 气相成分 

分 类 号：O484.1[理学—固体物理]