γ-氯丁酸酯相转移催化内环化反应新工艺研究  

STUDY ON THE PHASE TRANSFER CATALYTIC INTRAMOLECULAR CYCLIZATION REACTION OF γCHLOROBUTYRIC ESTER

作　　者：崔惠芳[1] 李天仚[1] 张文楠[1] 朱靖[1] 付长春[1] 

机构地区：[1]河南省科学院化学研究所,郑州450002

出　　处：《精细石油化工》2000年第3期25-27,共3页Speciality Petrochemicals

摘　　要：将相转移催化工艺引入 γ 氯丁酸酯脱氢卤内环化反应取代以甲醇钠为拂酸内环化剂的传统工艺 ,通过选择相转移催化剂品种及数量 ,反应溶剂品种 ,回流反应时间等工艺条件取得了相转移催化最佳工艺 。The phase transfer catalytic technology into intramolecular cyclization reaction of γchlorobutyric ester instead of traditional technology, with using sodium methoxide as acid scavenger and intramolecular cyclization agent, and with dangerous when processed, was studied. The optimum phase transfer catalytic technology was the type and amount of phase transfer catalysis, the reaction solvent type and the refluxing reaction time were disscussed.

关 键 词：相转移催化 内环化反应 拂酸剂 氯丁酸酯 工艺 

分 类 号：TQ225.3[化学工程—有机化工] TQ203.9