N-烯丙基吡啶氯盐离子液体/有机溶液复合溶剂对纤维素的溶解性能  

The Dissolution of Cellulose in N-Allylpyridinium Chloride Ionic Liquid/Organic Solvent

作　　者：赵地顺[1] 付林林[1] 任培兵[1,2] 李俊盼[1] 李贺[1] 

机构地区：[1]河北科技大学化学与制药工程学院,河北石家庄050018 [2]石家庄焦化集团有限责任公司,河北石家庄050031

出　　处：《高分子材料科学与工程》2012年第7期31-34,共4页Polymer Materials Science & Engineering

基　　金：国家自然科学基金资助项目(20976107)

摘　　要：采用一步法合成N-烯丙基吡啶氯盐离子液体([APy]Cl),用红外光谱(FT-IR)和核磁共振(1H-NMR)进行结构表征,并与常用有机溶液(二甲基亚砜(DMSO)、N,N-二甲基甲酰胺(DMF)、N,N-二甲基乙酰胺(DMAc)及吡啶)配成复合溶剂,测定并比较对棉浆粕的溶解能力。结果表明,四种复合溶剂均为纤维素的优良溶剂,其中在[APy]Cl/DMAc复合溶剂中溶解性能最佳,在100℃、DMAc质量分数为40%时,溶解度能达到12.25%。利用FT-IR、X射线衍射(XRD)和热重分析(TGA)对溶解再生前后纤维素膜的结构进行分析。结果表明,四种复合溶剂均为纤维素的直接溶剂,可将晶型由Ⅰ转变成Ⅱ,热稳定性良好。N-allylpyridinium chloride ionic liquid（Cl） was synthesized by one-step process,and its structure was characterized by 1H nuclear magnetic resonance spectrum（1H-NMR） and Fourier transform infrared spectra（FT-IR）.The dissolubilities of cotton pulp in Cl/common solvents（dimethylsulfoxide（DMSO）,N,N-dimethylformamide（DMF）,N,N-dimethylacetamide（DMAc） or pyridine） were measured and compared.The results show that four kinds of compound solvents are excellent solvent for cellulose,and the solubility in Cl/DMAc is better than in several other solvents under the same conditions.When the content of DMAc is 40%,the solubility of cotton pulp is up to 12.25% at 100 ℃.The original cellulose and the regenerated cellulose were analyzed by FT-IR,Xray diffraction（XRD） and thermogravimetric analysis（TGA）,respectively.The results show that these compound solvents are non-derivatizing solvents for cellulose and,make the crystal form of regenerated cellulose transform from celluloseⅠto celluloseⅡ.Furthermore,the regenerated cellulose shows good thermal stability.

关 键 词：离子液体 N N-二甲基乙酰胺 纤维素 溶解 

分 类 号：TQ413.29[化学工程]