700℃以上超超临界电站锅炉过热器管材用典型镍基合金的平衡析出相规律  

Equilibrium-phase precipitation behaviors of typical nickel-base alloys for 700 ℃ advanced ultra-supercritical boiler tubes

作　　者：王珏[1] 董建新[1] 张麦仓[1] 谢锡善[1] 

机构地区：[1]北京科技大学材料科学与工程学院,北京100083

出　　处：《北京科技大学学报》2012年第7期799-807,共9页Journal of University of Science and Technology Beijing

基　　金：国家自然科学基金资助项目(50831008)

摘　　要：利用热力学计算软件Thermo--Calc及镍基合金数据库,计算了三种700℃以上超超临界电站用过热器管道材料Inconel740、Inconel617和GH2984合金的热力学平衡相图,并对比了三种材料主要析出相的析出行为.计算结果表明:三种合金主要的析出相包括γ、γ'、碳化物、σ、η、δ、μ及α--Cr等,凝固过程中Mo、Nb和Ti元素偏析严重,会降低合金的初熔点,因此后期均匀化退火处理十分重要.另一方面,750℃时Inconel740合金γ'相析出量大于另外两种合金,并且Al和Ti含量对γ'相和η相析出行为有较大影响.碳化物的计算表明,Inconel617合金一次碳化物与另两种合金不同,并且其二次碳化物的析出温度范围最大.GH2984合金中Fe含量较大时会导致σ相出现,对合金的性能产生不利影响.Thermodynamic equilibrium phase diagrams of three candidate materials, Incone1740, Inconel617, and GH2984, for 700 ℃ advanced ultra-supercritical boiler tubes were calculated by Thermo-Cale software and nickel-base alloy databases. Precipitation behaviors of phases in the three alloys were investigated by comparison. There are similar equilibrium phases in the three alloys, inclu- dingγ, γ＇, carbides, α,η , δ, μ, and α-Cr. Serious segregations of No, Ti and Nb may occur during solidification based on the calculation, which would decrease the initial melting points of the three alloys; therefore the consequent homogenization treatment is quite important. On the other hand, the amount of γ＇ precipitated in Incone1740 is higher than that in the other two alloys at 750 ℃. A1 and Ti eontents can strongly effeet the precipitation of γ and γ phases. The calculation of carbides indicates that primary carbides in Ineonel617 are different from those in the other two alloys, and the precipitation temperature range of secondary carbides in Ineonel617 is larger. The presence of of in GH2984 alloy is harmful to the rneehanical orooerties due to a higher Po enntont

关 键 词：镍合金 析出相 碳化物 热力学 电站 

分 类 号：TG146.15[一般工业技术—材料科学与工程]