CeAlPO-5分子筛催化剂上二苯基甲烷选择性氧化生成二苯甲酮(英文)  

Selective Oxidation of Diphenylmethane to Benzophenone over CeAlPO-5 Molecular Sieves

作　　者：Subbiah DEVIKA Muthiahpillai PALANICHAMY Velayutham MURUGESAN 

机构地区：[1]Department of Chemistry,Anna University

出　　处：《催化学报》2012年第7期1086-1094,共9页

基　　金：supported by the Department of Science and Technology (DST, SR/S1/PC-10/2009);Government of India, New Delhi;the University Grants Commission (UGC), New Delhi

摘　　要：Selective oxidation of diphenylmethane to benzophenone requires active and selective catalysts. The framework incorporation of cerium in AlPO-5 molecular sieves creates active cerium sites in isolation. These active sites are responsible for selective oxidation. Cerium incorporated AlPO-5 with different Al/Ce ratios were synthesized, and the vapor phase oxidation of diphenylmethane in air over these catalysts was studied at 250, 275, 300, 325, and 350 °C. The diphenylmethane conversion and selectivity for benzophenone were more than 90%. CeAlPO-5(25) was found to be more active than other catalysts. The stability of the catalyst was verified by the time on stream study which indicated steady diphenylmethane conversion and benzophenone selectivity. Hence framework incorporated CeAlPO-5 molecular sieves are stable and active catalysts for the selective oxidation of diphenylmethane.Selective oxidation of diphenylmethane to benzophenone requires active and selective catalysts. The framework incorporation of cerium in AlPO-5 molecular sieves creates active cerium sites in isolation. These active sites are responsible for selective oxidation. Cerium incorporated AlPO-5 with different Al/Ce ratios were synthesized, and the vapor phase oxidation of diphenylmethane in air over these catalysts was studied at 250, 275, 300, 325, and 350 °C. The diphenylmethane conversion and selectivity for benzophenone were more than 90%. CeAlPO-5（25） was found to be more active than other catalysts. The stability of the catalyst was verified by the time on stream study which indicated steady diphenylmethane conversion and benzophenone selectivity. Hence framework incorporated CeAlPO-5 molecular sieves are stable and active catalysts for the selective oxidation of diphenylmethane.

关 键 词：CeAlPO-5 molecular sieve hydrothermal synthesis OXIDATION DIPHENYLMETHANE BENZOPHENONE 

分 类 号：O643.32[理学—物理化学] O625.42[理学—化学]